When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Stress corrosion cracking behaviour of 316l stainless. Although no stainless steel grade is totally immune. With its high chromium and molybdenum contents, it is able to. Stress corrosion cracking of an austenitic stainless steel in. In general, media that do not corrode 188 stainless steel tube will not attack these molybdenumcontaining grades. Controlling chloride induced stress corrosion cracking of.
To address the widely held concern that iso15156nace mr0175 limits for sour service cracking resistance of. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. Stress corrosion cracking of the aisi 316l stainless steel haz in a pwr nuclear reactor environment. One known exception is highly oxidizing acids such as nitric acid to which the molybdenumbearing. Selected properties of the halides and overview of observed modes of. Although the type 316 alloy is somewhat more resistant to scc than the 18 cr. Alloy c276 hastelloy c276 contains nickel, molybdenum, and chromium. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Development of stress corrosion cracking resistant welds. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides.
The test material 316l stainless steel was received in rolled plate condition. Corrosion of stainless steel type 316l in a seepage water. Ssc6mo uns n08367 is a superaustenitic 6% molybdenum alloy that exhibits far greater resistance to chloride pitting, crevice corrosion and stresscorrosion cracking than the. Chloride stress corrosion cracking of austenitic stainless steels can occur when the necessary conditions of temperature, tensile stress, oxygen, and chlorides are present. The high corrosion resistance of 316l allows for its use in chloride environments. Localized corrosion and stress corrosion cracking of stainless steels. For austenitic stainless steels chlorides are the major cause of stresscorrosion cracking scc. The impact of scc on a material usually falls between dry cracking and. Its high molybdenum content makes it exceptionally resistant to pitting and crevice corrosion, and it is one of only a few materials that can withstand the corrosive effects of wet chlorine. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries.
Stainless steel 316 and 316l grade 316 is the standard molybdenumbearing grade, second inoverall volume production to 304 amongst the austenitic stainless steels. Sensitized austenitic stainless steel suffers stress corrosion cracking scc in solutions of all. Stress corrosion cracking scc is a common issue with many specialty alloys. This paper presents the effect of buffing on the stress corrosion cracking scc resistance of machined surfaces of aisi 316l stainless steel ss. However, there is limited use with hydrochloric acids. The standard austenitic steels of the astm 304l and astm 316l types are prone to stress corrosion cracking scc in chloride bearing solutions at temperatures. Corrosion resistant metals materials selection guide. Properties of stainless steel 316l workstation industries. Pitting and stress corrosion cracking studies on aisi type. Corrosion resistance this is potentially the most important property and the reason for use of stainless steel grade 316l. Alloys 316, 316l, and 317l are more resistant to atmospheric and other mild types of corrosion than the 188 stainless steel.
Alloy 904l is a superaustenitic stainless steel that is designed for moderate to high corrosion resistance in a wide range of process environments. Pdf stress corrosion cracking of austenitic stainless. Since ss 316l has a much lower carbon content than ss316, the welding of 316l stainless steel is better than ss 316. Materials free fulltext stress corrosion cracking of. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress.
Stress corrosion cracking of the aisi 316l stainless steel. Aisi 316 vs 316l stainless steel, difference of ss316. Therefore, standard grades such as 304304l and 316316l are very. Corrosion behaviour of type 316l stainless steel in hot. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. High scc resistance of 316l stainless steel could be associated with. Stress corrosion cracking austenitic stainless steels are susceptible to stress corrosion cracking scc in halide environments. An example is hot potable water under heat transfer conditions which permit chlorides to. Austenitic steels of type astm 304 and 316 austenitic steels have limited resistance to stress corrosion cracking scc, even at very low chloride contents and. This mode of attack is termed stress corrosion cracking scc. Chlorideinduced stress corrosion cracking of powder. Therefore, it is important to determine the longterm general corrosion rates and susceptibility to localized corrosion. Surface finishing operations are known to lower the scc. Stainless steel provides both strength and corrosion resistance inside the concrete.
Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Chloride stress corrosion cracking and 316 stainless steel edstainless materials 20 jul 11 23. Localized corrosion resistance of stainless steel type 316l, a titaniumbased alloy ti0.
Aisi 304 stainless steel ss is one of the candidate materials used for dry storage canisters of spent nuclear fuel as an interim storage measure before final disposal 1,2. The occurrence of atmosphericinduced chloride stress corrosion cracking in types. The incubation time for crevice corrosion and pitting in seawater is relatively short, often only a few days. These alloys also offer higher creep, stress torupture and tensile strength at elevated temperature. The corrosion behaviour of type 316l stainless steel in aqueous 3050 wt%. Pdf atmosphericinduced stress corrosion cracking of austenitic. It also has a high resistance to pitting in chloride solutions, a high resistance to both crevice and stress corrosion cracking. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment.
Controlling chloride induced stress corrosion cracking of aisi 316l. Pdf since publication of ansinace mr0175iso 15156 in 2003 there has been much debate on the performance of austenitic stainless steels in oil and. Chloride stress corrosion cracking inspectioneering. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Types 316 and 316l are molybdenumbearing austenitic stainless steel which are more resistant to general corrosion and pittingcrevice corrosion than the conventional chromium nickel austenitic stainless steel such as type 304. In hot chloride environments, grade 316 is subject to pitting and crevice corrosion and to stress corrosion cracking when subjected to tensile stresses beyond about 50 o c. With a nickel content of 25%, 904l has proven to be a good alternative to most conventional stainless steels. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Addition of oxygen in autoclaves promoted the tendency to stress corrosion cracking. With its highly alloyed chemistry 25% nickel and 4. Stress corrosion cracking of an austenitic stainless steel.
Sour service limits of dualcertified 316316l steel twi. Outperforms alloys 304l and 316l in stress corrosion cracking resistance in chloride containing aqueous solutions its corrosion rate in boiling nitric acid 65% is higher than that of alloy 316l its high yield. Stress corrosion cracking facts and how to reduce the. Pdf inservice stress corrosion cracking of aisi 316l stainless. Chloride stress corrosion cracking clscc is one of the most common. Stress corrosion cracking of sensitized type 304 stainless. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Chloride stress corrosion cracking in austenitic stainless. The chlorideinduced stress corrosion cracking scc resistance of nitrogenalloyed, powder metallurgically pm produced and hot isostatically pressed hip duplex stainless. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. In addition, aisi 316 might lead to stresscorrosion cracking or dimensional instability in. Stresscorrosion cracking data generated by autoclave tests agreed well with the practical service conditions and can be used to discriminate alloys for scc resistance in sodium chloride solution. Stress corrosion cracking facts and how to reduce the risk.
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